Temporal stability and pressure calibration of barium carbonate and talc/pyrex pressure media in a piston-cylinder apparatus

Publication Status is "Submitted" Or "In Press: 
Yes
LDEO Publication: 
Yes
Publication Type: 
Year of Publication: 
2005
Authors: 
Editor: 
Journal Title: 
American Mineralogist
Journal Date: 
Jan
Place Published: 
Tertiary Title: 
Volume: 
90
Issue: 
1
Pages: 
206-218
Section / Start page: 
Publisher: 
ISBN Number: 
0003-004X
ISSN Number: 
Edition: 
Short Title: 
Accession Number: 
ISI:000226318500024
LDEO Publication Number: 
6692
Call Number: 
Abstract: 

New melting experiments in a 0.5 inch piston-cylinder apparatus from 0.5 to 3.0 GPa on compositions along the diopside-wollastonite join show that the eutectic liquid composition, which varies with pressure, does not change with time in experiments with barium carbonate or with talc/pyrex pressure media. Mapping out the trace of the diopside-wollastonite eutectic curve in P-T space with both piston-in and piston-out experiments reveals high-temperature pressure intensification in piston-in experiments with barium carbonate or talc/pyrex assemblies, in contrast to frictional loss of pressure at lower temperatures. A new pressure correction algorithm, derived by multiple regression analysis, incorporates both effects. When applied to a barium carbonate experiment at the intersection of the CMAS spinel-lherzolite to gamet-lherzolite transition (SGT) with the model peridotite solidus, the model pressure increases from 2.25 to 2.82 GPa. When a similar type of correction is applied to piston-out experiments run in talc/pyrex assemblies, the pressure of the intersection of the SGT and the CMAS solidus decreases from 3.0 to similar to2.9 GPa, in agreement with the barium carbonate experiments from this study and with experiments from other studies run with salt/pyrex assemblies.

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887PRTimes Cited:4Cited References Count:56

DOI: