Comparison of One-Color and 2-Color Ionization Schemes for the Analysis of Osmium and Rhenium Isotopic-Ratios by Sputter-Induced Resonance Ionization Mass-Spectrometry

Publication Status is "Submitted" Or "In Press: 
LDEO Publication: 
Publication Type: 
Year of Publication: 
1992
Editor: 
Journal Title: 
Analytical Chemistry
Journal Date: 
Nov 1
Place Published: 
Tertiary Title: 
Volume: 
64
Issue: 
21
Pages: 
2623-2627
Section / Start page: 
Publisher: 
ISBN Number: 
0003-2700
ISSN Number: 
Edition: 
Short Title: 
Accession Number: 
ISI:A1992JV78300028
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Key Words: 
Abstract: 

Sputter-induced resonance ionization mass spectrometry is a technique in which atoms sputtered from a sample are ionized using a pulsed laser beam. To maximize sample utilization, a pulsed ion beam is used to atomize the sample so there is a high temporal and spatial overlap between the atom plume and laser beam. The frequency of the laser is tuned to resonantly excite electrons in the atoms Into an excited state and then nonresonantly into the continuum. A two-color scheme which uses a portion of the excimer pump laser to excite the ionization step was investigated as a method of increasing the ionization signal. Ionization intensity enhancements in many transitions in Re and Os were measured. Isotope ratio measurements of Re filaments showed more sample to sample variations due to varying conditions of the laser beams and a higher blas than corresponding analyses of loaded samples.

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Jv783Times Cited:6Cited References Count:14

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