Groundwater record of halocarbon transport by the Danube River

Publication Status is "Submitted" Or "In Press: 
LDEO Publication: 
Publication Type: 
Year of Publication: 
1997
Editor: 
Journal Title: 
Environmental Science & Technology
Journal Date: 
Nov
Place Published: 
Tertiary Title: 
Volume: 
31
Issue: 
11
Pages: 
3293-3299
Section / Start page: 
Publisher: 
ISBN Number: 
0013-936X
ISSN Number: 
Edition: 
Short Title: 
Accession Number: 
ISI:A1997YE04000061
LDEO Publication Number: 
Call Number: 
Abstract: 

Groundwater dating studies have supported the concept that aquifers with low coefficients of dispersion may contain coherent records of past conditions in recharge areas. Groundwater records can provide unique information about natural or anthropogenic changes in the atmosphere and hydrosphere where long-term monitoring data are not available. Here we describe a 40-year record of halocarbon contamination in the Danube River that was retrieved from a shallow aquifer in northwest Hungary. The time scale is based on H-3 and He isotope dating of groundwaters that were recharged by the Danube River and moved horizontally away from the river in a surficial gravel aquifer with minor dispersion at a maximum rate of at least 500 m/yr. Analyses of dated groundwaters along a flow path indicate that the river loads of selected compounds (including CFC-12, CFC-113, and trichloroethane) were negligible before about 1950, rose rapidly to peak values in the 1960s and 1970s, and then decreased by varying degrees to the present. Peak concentrations are tentatively attributed to point sources in upstream urban-industrial centers; while recent decreases presumably resulted from declining manufacturing rates and(or) improvements in control of urban-industrial runoff and sewage effluent entering the river in upstream areas.

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Ye040Times Cited:5Cited References Count:47

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